Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline
نویسندگان
چکیده
Herein a novel inorganic-organic hybrid Keggin-type heteropolymolybdate [Ni2Na(C12H8N2)4(BMo12O40)(H2O)2] (1) has been synthesized under hydrothermal conditions in aqueous solution. The cyrstal structure was fully characterized by powder X-ray diffraction (XRD), elemental analysis, Fourier-tranform infrared spectrum (FT-IR), Thermogravimetric analysis (TGA) and Scanning Electron Microscopy (SEM) analysis. Single crystal structural demonstrates that the complex consists of Keggin anion [BMo12O40]5? polyanion, four 1,10-phenanthroline (C12H8N2) ligands, two Ni(II) ions, Na(I) ions aqua ligands. experimental (XRD) result is consistent with calculated data. SEM image shows compound crystals have cubic structure.
منابع مشابه
Hydrothermal Synthesis, Crystal Structure and Catalytic Properties of a Novel Polyoxometalate:
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ژورنال
عنوان ژورنال: Cumhuriyet Science Journal
سال: 2021
ISSN: ['2587-2680', '2587-246X']
DOI: https://doi.org/10.17776/csj.812164